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All the templates in XOOPS are stored in the Database. When first installing XOOPS and hading upload all the files to your server, during the installation process the content of the templates files is saved in the DB. When cloning a temlate set, the new cloned template is also stored in the DB only. When installing a XOOPS module, the content of its templates files is also stored to the Database. So everything is in the DB! When editing a cloned template set the changes are saved in the DB. So to change a template you have to do it through the templates managing pages in your admin area.
I think it would also work if you change what you need in the templates files of a module, then upload the files to the server on the place of the original and finally Update the module through the Modules administration page. But it's not a good way and it's not easier at all. So clone the original template and then just use the XOOPS admin interface to do what changes you need.
Good luck!