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Mate i had so much trouble with php, iis and MySQL running together in win XP pro. I decided to go with easy php, which is like a mini IIS kinda, not really, no, but it has a gui and is good for newbies. Have a look at
http://www.easyphp.org. DITCH M$ and IIS on this one mate, trust me!
Have fun! Lol.
"When life hands you a lemon, throw it at someone!"- John Rzeznik, Goo Goo Dolls