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I'd be happy to join the Documentation Team, and do what I can to help. I planned on writing a FAQ for core modules for my users anyway (and, believe me, they have a LOT of questions to answer, lol), as well as one for xcGallery and any other add-on module I decided to use. I suppose the FAQ would carry over to XOOPS in general, and would benefit other end users (the core modules work pretty much the same for everyone).
I think it would be really great to have a downloadable FAQ that would cover the core modules for end users to a site, so they have something to refer to when they log on for the first time. Maybe bundle it up with the full install or something, too. I think any administrator would welcome that. It's just one less thing they would have to do.
This would be a good opportunity for me to give back to the XOOPS community and to help it keep growing. It's the least I could do. XOOPS was a godsend when I found it. Shoot me an email if you think I could be of help.