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So.. i'm in the same boat as madsen, in that i've a few people in the webmaster group who's lives have become too busy to deal with the responsability (and the deluge of registration emails) and consequently would like to be removed from the webmaster group.
I'm running 2.0.6 as well, and when I try to remove them, i click on submit and get a blank page.
I've tried using both sql and php debugging, but they don't even come up.
HELP!!!
(btw.. when removing someone from a group.. the button does say delete.. so I'm sure that may have caused some confusion)