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You may be correct, perhaps it would be better to seperate the desired abilities into two groups. One would be for module testing, the other for theme testing:
Module Testing:
1. Strong php background
2. Familiarity with the XOOPS Core Classes / Functions
Theme Testing:
1. Smarty Knowledge
2. CSS Knowledge
3. (should have had this one at the beginning) Ability to test within multiple browsers
Having a strong attention to detail and good communcation skills are secondary, but still important.