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Hi,
Provisioning API does provide a way to programmatically create and
manage user accounts.
The PHP client library is available for download here:
http://code.google.com/apis/apps/libraries_and_samples.html
Also, here is a link to PHP Provisioning API v2.0 developer's guide that details the API with sample code:
http://code.google.com/apis/apps/gdata_provisioning_api_v2.0_reference_php.html
See:
http://framework.zend.com/download/gdata/
http://code.google.com/apis/apps/overview.html