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Ok guys,I found the same problem but I know how to fix it now.
I use Apache v2.0.55,MySql v5.0.18 and PHP v5.1.2.
1.You have to download MySQL Connector/PHP from
http://dev.mysql.com/downloads/connector/php/,it depend on your MySQL version. Then unpack it.
2.Create Extension folder in C:/php,e.g. C:/php/extensions
3.Copy file php_mysql.dll (It is the file downloded from step 1) to C:/php/extensions.
4.Open php.ini file , typical location file is C:\PHP\php.ini, and searching the following line
"extension_dir= " configure the line for example
extension_dir = C:\php\extensions.
5.Then search this line ";extension=php_mysql.dll"
and comment ";" out .
6.Copy the libmysql.dll to the PHP installation directory
,e.g. c:\php
7.Restart MySQL service.
8.Try to install XOOPS again.
Good luck....
Mr.Momo