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I dont know how technical you are, so hope you dont think I am teaching you to suck eggs.
First of all I would try to ping the server. (Start->Run) then type cmd, in the dos box type Ping {your server IP address}
If you get a reply from {your server}, then you PC can at least see the web server.
You could also see what route your PC is taking to reach the server. It could be that the PC is always going down the VPN tunnle. In the a cmd box again, type
tracert {your server IP Address} and see what hops it does to reach the server. You should be able to see if it is going down the VPN.
Also try to ping the PC from the server. You should also check the default gateway on the server, it could be that you web request from the PC is reaching the server but then the server is sending the response down the VPN tunnle.
Let us know the results.
Simon
Whats on in Preston
http://www.prestondocks.net