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Hi Xetox,
As long as your XOOPS version are the same (to keep things simple) it should not be too hard.
Use PhpMyAdmin (or an other database administration tool) to export the table(s) with users form the old DB and use the same tool to import the table(s) into the new DB.
for XOOPS 2.0.13.2 (my version) you will need to export the following table : "
_users" and for the permissions you'll need to do the same for "_groups_users_link" and "_groups".
Use the export function to make a full backup (all tables) first just incase you press the wrong buttons !!
Hope this helps, Highlander