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You can access XOOPS only with the URL you have given in the mainfile.php
If you have the following:
define('XOOPS_URL', 'http://localhost');
You access XOOPS with
http://localhostSupposed your PC have the following IP you can write:
define('XOOPS_URL', 'http://192.168.0.10');
then you can access XOOPS with the IP.
If you are running XOOPS as an intranet site
you can define the following:
define('XOOPS_URL', 'http://intranet');
If you have a DNS running within your intranet make an entry.
If not, make an entry into every PC's hosts file.