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Hi chrisis,
What is the uid affected?
If you know what the bad link is and have phpMyAdmin access to your XOOPS DB, go to the table xoops_session find the offending session that is referenced in your link and remove it.
If you don't know the bad link, I'd suggest 2 things: first, register a new user (don't login yet, just create a new user and finish registration), login as admin and quickly go to your URL/modules/system/admin.php?fct=preferences&op=show&confcat_id=1 and set "use custom session" to true, and even more quickly go to groups and add the new user to the webmasters group, then remove the affected admin user from it. Now, this can be dangerous, so if you can create a backup of your site and try these modifications in a test server, do it first.
Perhaps just deleting all sessions from that table will work too?